TY - BOOK AU - Lunn,George AU - Sansone,E.B. TI - Destruction of hazardous chemicals in the laboratory SN - 9781119848806 AV - TD1050.S24 L86 2023 U1 - 628.4/2 23/eng/20220906 PY - 2023/// CY - Hoboken, NJ PB - John Wiley & Sons, Inc. KW - Hazardous wastes KW - Safety measures KW - Chemical laboratories KW - Chemicals KW - Electronic books N1 - Includes bibliographical references and index; Table of Contents Preface xi Acknowledgments xiii Introduction 1 Safety considerations 9 Nitrosamine Formation 12 Sodium Hypochlorite 15 Nickel–Aluminum Alloy 18 Potassium Permanganate 19 Specific Methods for the Destruction of Hazardous Chemicals in the Laboratory 25 Acetonitrile 27 Acid Halides and Anhydrides 31 Aflatoxins 35 Alkali and Alkaline Earth Metals 43 Alkali Metal Alkoxides 47 Anatoxin-A 49 Aromatic Amines 53 Arsenic 61 Azides 65 Azo and Azoxy Compounds and Tetrazenes 73 Boron Trifluoride and Inorganic Fluorides 79 Botulinum Toxins 83 Brevetoxins 87 Butyllithium 91 Calcium Carbide 95 Carbamic Acid Esters 97 Carbofuran 101 Chloromethylsilanes and Silicon Tetrachloride 103 N-Chlorosuccinimide and Chloramine-T 105 Chlorosulfonic Acid 107 Chromium(VI) 109 Citrinin 115 Complex Metal Hydrides 123 Cyanides and Cyanogen Bromide 129 Cylindrospermopsin 137 Diisopropyl Fluorophosphate 141 Dimethyl Sulfate and Related Compounds 149 Dyes and Biological Stains 161 Ethidium Bromide 195 Haloethers 203 Halogenated Compounds 207 Halogens 223 Heavy Metals 227 Hexamethylphosphoramide 233 Hydrazines 235 Hypochlorites 247 Mercury 251 2-Methylaziridine 257 1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine (MPTP) 261 Microcystins 265 4-Nitrobiphenyl 275 3-Nitrofluoranthene and 3-Aminofluoranthene 277 Nitrogen Tetroxide 281 N-Nitroso Compounds: Nitrosamides 283 N-Nitroso Compounds: Nitrosamines 295 Ochratoxin A 307 Okadaic Acid 315 Organic nitriles 319 Osmium tetroxide 321 Palytoxin 323 Patulin 327 Peracids 333 Perchlorates 335 Peroxides and Hydroperoxides 339 Phenol 343 Phosgene 347 Phosphorus and Phosphorus Pentoxide 351 Picric Acid 355 Polycyclic Aromatic Hydrocarbons 357 Polycyclic Heterocyclic Hydrocarbons 367 Potassium Permanganate 381 β-Propiolactone 383 Protease Inhibitors 385 Ricin 389 Saxitoxin 393 Selenium Compounds 397 Sodium Amide 399 Sterigmatocystin 401 Sulfonyl Fluoride Enzyme Inhibitors 407 Sulfur-Containing Compounds 413 T-2 Toxin and Other Tricothecenes 419 Tetrodotoxin 425 Triacetone Triperoxide 429 Uranyl Compounds 433 Destruction of Pharmaceuticals 437 General Considerations 439 Potassium Permanganate 451 Nickel–Aluminum Alloy Reduction 467 Fenton Reaction 473 Hydrogen Peroxide 479 Ozone 481 Ferrate 497 Persulfate 505 Hydrogen Peroxide and Horseradish Peroxidase 513 Specific Degradation Procedures for ß-Lactams 515 Decontamination of Aqueous Solutions 517 Miscellaneous Chemical Degradation Procedures 523 General Considerations for Photolytic Procedures 535 Photolysis Without Added Reactants (UV Only) 537 Photolysis with Hydrogen Peroxide (UV/H2O2) 555 Photo-Fenton Reaction 573 Photolysis with Titanium Dioxide (UV/TiO2) 589 Photolysis with Zinc Oxide (UV/ZnO) 605 Photolysis with Ozone (UV/O3) 609 Photolysis with Persulfate (UV/Persulfate) 615 Photolysis with Chlorine (UV/Cl2) 631 Miscellaneous Photolytic Procedures (UV/Miscellaneous) 643 Procedures Classified by Method 649 General Considerations 651 Potassium Permanganate 655 Fenton Reaction 659 Ozone 667 Persulfate 677 Miscellaneous Procedures 683 Photolysis Without Added Reactants (UV only) 691 Photolysis with Hydrogen Peroxide (UV/H2O2) 697 Photo-Fenton Reaction 707 Photolysis with Titanium Dioxide (UV/TiO2) 715 Photolysis with Zinc Oxide (UV/ZnO) 727 Photolysis with Ozone (UV/O3) 735 Photolysis with Persulfate (UV/Persulfate) 741 Photolysis with Chlorine (UV/Cl2) 747 Biologicals 751 Appendixes 777 Appendix I: Procedures for Drying Organic Solvents 779 Appendix II: Safety Considerations With Potassium Permanganate 783 Cross-Index of Names for Dyes and Biological Stains 791 Cross-Index of Methods Used for Specific Dyes and Biological Stains 813 Cross-Index of Methods Used for Pharmaceuticals 817 Name Index 837; Available to OhioLINK libraries N2 - "The book describes practical procedures for the destruction of hazardous chemicals in the laboratory in which they are used. Exotic reagents and equipment are not required. There has been an enormous expansion in work aimed at the large-scale destruction of hazardous chemicals before or after they enter the environment. This new edition great expands the sections on Methods for the Destruction of Pharmaceuticals in the Laboratory and Procedures Classified by Method. Building on the revised and extended content of the previous editions, many procedures are described in detail and analytical methods that can be used to test for completeness of destruction are provided. In many cases the final reaction mixtures were tested for mutagenic activity. Recent work cited in the literature has been mined for procedures that can be used in the laboratory. Almost all of the procedures come from articles in peer-reviewed journals. Unlike most other sources this book describes the critical aspects of the various protocols (e.g., UV lamp type, rate of ozone flow). Numerous tables throughout the book allow for ready comparison of procedures. The book is used by researchers in the laboratory to help in getting rid of residual amounts of hazardous chemicals when the series of experiments has ended. These procedures can also be incorporated in laboratory protocols. The book is also useful to laboratory safety officers who may be called upon to give advice to researchers"-- UR - https://onlinelibrary.wiley.com/doi/book/10.1002/9781119848851 ER -